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To download Adobe apps, you will need to download and install Creative Cloud on your PC or Mac. From Creative Cloud, you can then install any of the Adobe apps (Acrobat, Photoshop, Illustrator, etc.).
Download Creative Cloud from here: https://creativecloud.adobe.com/apps/download/creative-cloud.
Run the installer.
When prompted to log in with an Adobe ID, enter your DE email address. If asked what type of Adobe ID you have, select Company/School Account or Enterprise ID. Your password is your DE password.
Once Creative Cloud finishes installing, you can install and launch any of the Adobe apps through the Creative Cloud app.
See Adobe's answer: https://helpx.adobe.com/download-install/using/install-apps-number-of-computers.html
(Adobe Creative Cloud administration for CS.)